[1] SCHWARZ K,MERTZ W.Chromium (Ⅲ) and the glucose tolerance factor[J].Archives of Biochemistry and Biophysics,1959,85(1):292-295.

[2] CONNETT P H,WETTERHAHN K E.
In vitro reaction of the carcinogen chromate with cellular thiols and carboxylic acids[J].Journal of the American Chemical Society,1985,107(14):4282-4288.

[3] O'BRIEN T J,CERYAK S,PATIERNO S R.Complexities of chromium carcinogenesis:role of cellular response,repair and recovery mechanisms[J].Mutation Research:Fundamental and Molecular Mechanisms of Mutagenesis,2003,533(1/2):3-36.
[4] GUNARATNAM M,GRANT M H.Cr (Ⅵ) inhibits DNA,RNA and protein syntheses in hepatocytes:involvement of glutathione reductase,reduced glutathione and DT-diaphorase[J].Toxicology
in Vitro,2008,22(4):879-886.

[5] KUMAR K M,ARULDHAS M M,BANU S L,et al.Male reproductive toxicity of CrⅥ:
in-
utero exposure to CrⅥ at the critical window of testis differentiation represses the expression of Sertoli cell tight junction proteins and hormone receptors in adult F1 progeny rats[J].Reproductive Toxicology,2017,69:84-98.
[6] SUBRAMANIAN S,RAJENDIRAN G,SEKHAR P,et al.Reproductive toxicity of chromium in adult bonnet monkeys (
Macaca radiata Geoffrey).Reversible oxidative stress in the semen[J].Toxicology and Applied Pharmacology,2006,215(3):237-249.

[7] GREENE L E,RIEDERER A M,MARCUS M,et al.Associations of fertility and pregnancy outcomes with leather tannery work in Mongolia:a pilot study[J].International Journal of Occupational and Environmental Health,2010,16(1):60-68.

[8] ZIAEE H,DANIEL J,DATTA A K,et al.Transplacental transfer of cobalt and chromium in patients with metal-on-metal hip arthroplasty:a controlled study[J].The Journal of Bone and Joint Surgery,2007,89(3):301-305.
[9] 查龙应.不同化学形式三价铬肠道吸收机理的研究[D].博士学位论文.杭州:浙江大学,2007.
[10] CHEN J,WANG Z S,ZHOU A G.Effect of small peptide chelate chromium on growth performance,organ development and serum traits in spargue-dawley rats[J].Pakistan Journal of Nutrition,2009,8(7):912-916.

[11] ANDERSON R A,BRYDEN N A,POLANSKY M M,et al.Dietary chromium effects on tissue chromium concentrations and chromium absorption in rats[J].The Journal of Trace Elements in Experimental Medicine,1996,9(1):11-25.

[12] AGUILAR F,DUSEMUND B,GALTIER P,et al.Scientific opinion on the safety of trivalent chromium as a nutrient added for nutritional purposes to foodstuffs for particular nutritional uses and foods intended for the general population (including food supplements)[J].EFSA Journal,2010,8(12):1882.
[13] LAMSON D W,PLAZA S M.The safety and efficacy of high-dose chromium[J].Alternative Medicine Review,2002,7(3):218-235.
[14] FENG W Y.The transport of chromium (Ⅲ) in the body[M]//VINCENT J B.The nutritional biochemistry of chromium (Ⅲ).Elsevier:Amsterdam,2007:121-137.
[15] HOPKINS L L,Jr,SCHWARZ K.Chromium (Ⅲ) binding to serum proteins,specifically siderophilin[J].Biochimica et Biophysica Acta:General Subjects,1964,90(3):484-491.

[16] FENG W Y,LI B,LIU J,et al.Study of chromium-containing proteins in subcellular fractions of rat liver by enriched stable isotopic tracer technique and gel filtration chromatography[J].Analytical and Bioanalytical Chemistry,2003,375(3):363-368.

[17] LINDEMANN M D,CROMWELL G L,MONEGUE H J,et al.Effect of chromium source on tissue concentration of chromium in pigs[J].Journal of Animal Science,2008,86(11):2971-2978.

[18] NRC.Mineral tolerance of animals[S].Washington,D.C.:The National Academies Press,2005:510.
[19] BORTOLOZZO F P,PINHEIRO MACHADO I,WENTZ I,et al.Effect of chromium picolinate on swine reproduction.1.Influence on number of ovulations,number of viable embryos and embryo survival[C]//Proceedings of the 15th International Pig Veterinary Society Congress. Birmingham,England:Nottingham University Press,1998:79.
[20] HAGEN C D, LINDEMANN M D, PURSER K W,et al.Effect of dietary chromium tripicolinate on productivity of sows under commercial conditions[J]. Journal of Swine Health and Production,2000,8(2),59-63.
[21] LINDEMANN M D,WOOD C M,HARPER A F,et al.Dietary chromium picolinate additions improve gain:feed and carcass characteristics in growing-finishing pigs and increase litter size in reproducing sows[J].Journal of Animal Science,1995,73(2):457-465.

[22] LINDEMANN M D,HARPER A F,KORNEGAY E T.Further assessment of the effects supplementation of chromium from chromium picolinate on fecundity in swine[J].Journal of Animal Science,1995,73(Suppl.1):185.
[23] 贾瑞莲,鲍宏云.蛋氨酸铬对母猪繁殖性能的影响[J].饲料工业,2012,33(16):57-58.
[24] WANG L S,SHI Z,JIA Z Q,et al.The effects of dietary supplementation with chromium picolinate throughout gestation on productive performance,Cr concentration,serum parameters,and colostrum composition in sows[J].Biological Trace Element Research,2013,154(1):55-61.

[25] 黄志坚,黄依明,林藩平.两种有机铬对母猪繁殖的效应试验[J].养猪,2001(4):9-10.
[26] 梁贤威,夏中生,陆呈委,等.有机铬对母猪繁殖性能及其仔猪生长的影响[J].粮食与饲料工业,2002(11):35-36.
[27] DINAKARPANDIAN D,MORRISSETTE V,CHAUDHARY S,et al.An informatics search for the low-molecular weight chromium-binding peptide[J].BMC Chemical Biology,2004,4(1):2.
[28] YAMAMOTO A,WADA O,MANABE S.Evidence that chromium is an essential factor for biological activity of low-molecular-weight,chromium-binding substance[J].Biochemical and Biophysical Research Communications,1989,163(1):189-193.

[29] CEFALU W T.Mechanism of action of chromium:cellular signaling[J].Presentation at Chromium in Health and Disease,A CADRE Research Summit.2003:1-2.
[30] CEFALU W T,WANG Z Q,ZHANG X H,et al.Oral chromium picolinate improves carbohydrate and lipid metabolism and enhances skeletal muscle Glut-4 translocation in obese,hyperinsulinemic (JCR-LA corpulent) rats[J].The Journal of Nutrition,2002,132(6):1107-1114.

[31] CEFALU W T,MARTIN J M,WACHTEL D,et al.Chromium picolinate supplementation increases insulin-stimulated Akt phosphorylation
in vivo in skeletal muscle from subjects with type 2 diabetes[C]//18th International Diabetes Federation Congress.Belgium:International Diabetes Federation.2003:24-29.
[32] LIU L J,WANG B,HE Y D,et al.Effects of chromium-loaded chitosan nanoparticles on glucose transporter 4,relevant mRNA,and proteins of phosphatidylinositol 3-kinase,Akt2-kinase,and AMP-activated protein kinase of skeletal muscles in finishing pigs[J].Biological Trace Element Research,2017,178(1):36-43.

[33] LINDEMANN M D.Use of chromium as an animal feed supplement[M]//VINCENT J B.The nutritional biochemistry of chromium (Ⅲ). Elsevier:Amsterdam,2007:85-118.
[34] COX N M,STUART M J,ALTHEN T G,et al.Enhancement of ovulation rate in gilts by increasing dietary energy and administering insulin during follicular growth[J].Journal of Animal Science,1987,64(2):507-516.

[35] WHITLEY N C,MOORE A B,COX N M.Comparative effects of insulin and porcine somatotropin on postweaning follicular development in primiparous sows[J].Journal of Animal Science,1998,76(5):1455-1462.

[36] RAMIREZ J L,COX N M,MOORE A B.Influence of exogenous insulin before breeding on conception rate and litter size of sows[J].Journal of Animal Science,1997,75(7):1893-1898.

[37] DONG F,KANDADI M R,REN J,et al.Chromium (
D-phenylalanine)3 supplementation alters glucose disposal,insulin signaling,and glucose transporter-4 membrane translocation in insulin-resistant mice[J].The Journal of Nutrition,2008,138(10):1846-1851.

[38] HOFFMAN N J,PENQUE B A,HABEGGER K M,et al.Chromium enhances insulin responsiveness via AMPK[J].The Journal of Nutritional Biochemistry,2014,25(5):565-572.

[39] 田耀耀,张丽英,朱琳,等.蛋氨酸铬对猪血液生化指标和激素水平及免疫球蛋白的影响[J].中国畜牧杂志,2016,52(17):37-41.
[40] 王敏奇,许晓玲,雷剑,等.不同形式三价铬对肥育猪胴体组成和脂肪代谢的影响[J].畜牧兽医学报,2009,40(1):59-65.
[41] WOODWORTH J C,TOKACH M D,NELSSEN J L,et al.Influence of dietary
L-carnitine and chromium picolinate on blood hormones and metabolites of gestating sows fed one meal per day[J].Journal of Animal Science,2007,85(10):2524-2537.

[42] 张敏红,张卫红,杜荣,等.补铬对高温环境下猪的铬代谢、生理生化反应和生产性能的影响[J].畜牧兽医学报,2000,31(1):1-8.
[43] VAN DE LIGT J L G,LINDEMANN M D,HARMON R J,et al.Effect of chromium tripicolinate supplementation on porcine immune response during the postweaning period[J].Journal of Animal Science,2002,80(2):449-455.

[44] JAIN S K,KANNAN K.Chromium chloride inhibits oxidative stress and TNF-α secretion caused by exposure to high glucose in cultured U937 monocytes[J].Biochemical and Biophysical Research Communications,2001,289(3):687-691.

[45] JAIN S K,ROGIER K,PROUTY L,et al.Protective effects of 17β-estradiol and trivalent chromium on interleukin-6 secretion,oxidative stress,and adhesion of monocytes:relevance to heart disease in postmenopausal women[J].Free Radical Biology and Medicine,2004,37(11):1730-1735.

[46] JAIN S K,RAINS J L,CROAD J L.Effect of chromium niacinate and chromium picolinate supplementation on lipid peroxidation,TNF-α,IL-6,CRP,glycated hemoglobin,triglycerides,and cholesterol levels in blood of streptozotocin-treated diabetic rats[J].Free Radical Biology and Medicine,2007,43(8):1124-1131.

[47] TAN G Y,BI J M,ZHANG M H,et al.Effects of chromium picolinate on oxidative damage in primary piglet hepatocytes[J].Biological Trace Element Research,2008,126(Suppl.1):69-79.