Selection of Calibration Reference Value for Near-Infrared Reflectance Spectroscopy Quantitative Analysis Model of Vitamin E in Premix

FAN Xia; JIANG Xunpeng; WANG Shi; SONG Jincai; TIAN Shuli; ZHENG Xuecong

doi:10.3969/j.issn.1006-267x.2022.03.056

2022 , Vol. 34 >Issue 3: 1975 - 1983

DOI: https://doi.org/10.3969/j.issn.1006-267x.2022.03.056

RESEARCH PAPER

Selection of Calibration Reference Value for Near-Infrared Reflectance Spectroscopy Quantitative Analysis Model of Vitamin E in Premix

FAN Xia ,
JIANG Xunpeng ,
WANG Shi ,
SONG Jincai ,
TIAN Shuli ,
ZHENG Xuecong

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1. Institute of Quality Standards & Testing Technology for Agro-Products, Chinese Academy of Agricultural Sciences, Beijing 100081, China;
2. Bluestar Adisseo Nanjing Co., Ltd., Nanjing 210048, China;
3. COFCO(Beijing) Feed Technology Co., Ltd., Beijing 100081, China

Received date: 2021-07-05

Online published: 2022-03-14

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Abstract

The purpose of this study was to compare the prediction accuracy difference of two kinds of near-infrared reflectance spectroscopy (NIRS) quantitative analysis models which with the detected value as the calibration reference value and with the theoretical value as the calibration reference value. A total of 225 vitamin premix samples were prepared, the NIRS of all samples with a range of 10 000 to 4000 cm^-1 were collected by Fourier transform near-infrared spectrometer. Two NIRS quantitative analysis models of vitamin E were constructed based on the detection value and theoretical value as the calibration reference value, respectively, with same calibration set of vitamin premix, partial least square method and the optimal spectral pretreatment method. According to the F-test, the same independent validation set was used to evaluate the prediction effect of NIRS quantitative analysis model. The results showed that the NIRS quantitative analysis model A (Model-A) of vitamin E taken the detected value as the calibration reference value, the optimal spectral preprocessing method was multivariate scattering correction, the determination coefficient (R²) of the calibration set was 0.992, the root mean square error of cross validation (RMSECV) was 4.50×10³ IU/kg, and the ratio performance deviation (RPD) was 11.2. The NIRS quantitative analysis model B (Model-B) of vitamin E taken the theoretical value as the calibration reference value, the optimal spectral pretreatment method was standard normal variate, the R² of the calibration set was 0.991, the RMSECV was 4.94×10³ IU/kg, and the RPD was 10.6. At confidence level α=0.05, the F-values of the 2 models were 5.48 and 3.77, respectively, which are higher than F_0.05(2,60)=3.15. In conclusion, it is feasible to choose the theoretical value as the calibration reference value to construct the NIRS quantitative analysis model of vitamin E at the confidence level of α=0.05, however, the prediction error will increase after the vitamin premix is stored for more than 7 days.

Key words： NIRS; calibration reference value; vitamin premix

Cite this article

FAN Xia , JIANG Xunpeng , WANG Shi , SONG Jincai , TIAN Shuli , ZHENG Xuecong . Selection of Calibration Reference Value for Near-Infrared Reflectance Spectroscopy Quantitative Analysis Model of Vitamin E in Premix[J]. Chinese Journal of Animal Nutrition, 2022 , 34(3) : 1975 -1983 . DOI: 10.3969/j.issn.1006-267x.2022.03.056

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